A one-dimensional inorganic–organic hybrid compound: catena-poly[ethylenediammonium [indate(III)-di-μ-hydrogenphosphato(V)-μ-hydroxido] monohydrate]
نویسندگان
چکیده
The title compound, (C(2)H(10)N(2))[In(HPO(4))(2)(OH)]·H(2)O, was synthesized under hydro-thermal conditions. The structure of this hybrid compound consists of isolated inorganic chains with composition (∞)[In(HPO(4))(4/2)(OH)(2/2)] running along [010]. The coordination of the In(III) atom is distorted octa-hedral. The ethyl-enediammonium cation and the disordered water mol-ecule (site-occupation factors = 0.7:0.3) ensure the cohesion of the structure via N-H⋯O and O-H⋯O hydrogen bonds.
منابع مشابه
The one-dimensional organic–inorganic hybrid: catena-poly[bis[1-(3-ammoniopropyl)-1H-imidazolium] [[iodidoplumbate(II)]-tri-μ-iodido-plumbate(II)-tri-μ-iodido-[iodidoplumbate(II)]-di-μ-iodido]]
The organic-inorganic hybrid, {(C(6)H(13)N(3))(2)[Pb(3)I(10)]}(n), was obtained by the reaction of 1-(3-ammonio-prop-yl)imidazolium triiodide and PbI(2) at room temperature. The structure contains one-dimensional {[Pb(3)I(10)](4-)}(n) polymeric anions spreading parallel to [001], resulting from face-face-edge association of PbI(6) distorted octa-hedra. One of the Pb(II) cations is imposed at an...
متن کاملA novel inorganic–organic hybrid borate, poly{[Na2(C4H2O4)(H3BO3)(H2O)4]·H3BO3}
The structure of the title compound, catena-poly[[[di-μ-aqua-μ-fumarato-μ-(boric acid)-disodium]-di-μ-aqua] boric acid monosolvate], contains two crystallographically independent Na(+) cations, each being six-coordinated by one fumarate O atom, one boric acid O atom and four water O atoms in a distorted octa-hedral geometry. Adjacent [NaO(2)(OH(2))(4)] units share edges and are linked into chai...
متن کامل{[Na1(μ-H2O)Na2]2[(C2O4)2Cr(μ-OH)2Cr(C2O4)2]·H2O}n, a novel hydrated form
The unit cell of the title compound, poly[[μ-aqua-μ-hydroxido-di-μ-oxalato-chromium(III)disodium] monohydrate], {[CrNa(2)(C(2)O(4))(2)(OH)(H(2)O)]·H(2)O}(n), contains four [Na1(μ-H(2)O)Na2][(C(2)O(4))(2)Cr(μ-OH)·H(2)O] formula units, each of which consists of two crystallographically independent Na(+) sites (bridged by one aqua ligand), one half of a centrosymmetric di-μ-hydroxido-bis-[cis-bis-...
متن کاملcatena-Poly[bis(1,3-benzothiazol-3-ium) [[dichloridoantimonate(III)]-di-μ-chlorido-μ-oxido-[chloridoantimonate(III)]-μ-chlorido]]
The title compound, {(C7H6NS)2[Sb2Cl6O]} n , contains two benzo-thia-zolidium cations and one tri-μ-chlorido-tri-chlorido-μ-oxido-di-anti-monate(III) anion. The structure of the inorganic cation may be described as as being built up from two polyhedra, i.e. a square-pyramidal SbCl4O and a distorted octa-hedral SbOCl5 unit, sharing a common face (comprising the O atom and two Cl atoms). The two ...
متن کاملPoly[ethylenediammonium [tris[μ3-hydrogenphosphato(2−)]dicadmium] monohydrate]
The title compound, {(C(2)H(10)N(2))[Cd(2)(HPO(4))(3)]·H(2)O}(n), was synthesized under hydro-thermal conditions. The structure of this hybrid compound consists of CdO(6), CdO(5) and PO(4) polyhedra arranged so as to build an anionic inorganic layer, namely [Cd(2)(HPO(4))(3)](2-), parallel to the ab plane. The edge-sharing CdO(6) octa-hedra form infinite chains running along the a axis and are ...
متن کامل